The Battery of Batteries

MINOLTA DIGITAL CAMERABy The Metric Maven

Bulldog Edition

When I first discovered batteries as a young boy, I was fascinated, but this feeling would soon turn to disappointment. I had small flashlights, and small toy cars that would quickly drain the batteries, and then the fun was over. I had no way to obtain new batteries, but my father purchased a “home battery charger.” It could hold batteries from AA to D and when they were done “recharging” a neon light would shut off. I very quickly discovered  that “recharged” batteries would discharge at such a fast rate that it was almost a waste of time to charge them. I cut open dry cells and other batteries to see what was inside until my curiosity was satisfied.

Willard-Storage-Batteries-1925-Clean

1925 Advertisement for batteries

I encountered batteries again when I was studying for my Professional Engineering (PE) exam. What I learned was there are two kinds of batteries. The first type of batteries are single use. After they have been discharged they cannot be recharged. These are called a primary cells. Primary cells undergo a chemical change which is not reversible. The second type are those that are chemically reversible, and rechargeable. These batteries are called secondary cells. The number of times a secondary cell can be recharged is finite. My PE reference states that:

The cycle life is the number of times a battery can be discharged or charged before the output voltage drops to a prescribed value. A cycle is a predetermined number of amp-hours (A*h) of discharge or charge.

When I first encountered the idea of ampere-hours (amp-hours?–tsk—tsk) it seemed to make sense. I found it quite interesting that primary cells had a lower “service capacity” depending upon the magnitude of current drawn from them:

PE-ReferenceWhat this table does not reveal is the total energy extraction possible. To argue that mA*h is an energy term is misleading, this is an energy metaphor. In my view the best way to describe the total available energy in the battery would be in joules. Assuming these are all 1.5 volt cells, then in my view the table should have a third entry:

Energy Capacity (J)      Starting Drain Current (mA)         Service Capacity (h)
AAA

3132                                            2                                             290
2430                                          10                                              45
1840                                          20                                              17

AA

5670                                            3                                             350
3240                                          15                                              40
2430                                          30                                              15

C

11 610                                           5                                            430
13 500                                         25                                            100
10 800                                         50                                              40

D

27 000                                          10                                            500
28 350                                          50                                            105
24 300                                         100                                            45

One could argue whether the energy capacity should be the final column or the first. The energy values are all in the Kilojoule range, and so could have been written with decimal points to emphasize the magnitude more directly. In a previous blog we see that a common Subway sandwich is around 1000 Kilojoules (six inch sandwiches in Australia?—tsk–tsk–how about Subway “150 sandwiches”?). This provides some context for the energy involved.

One can immediately note that the total amount of energy one can extract from a AAA battery depends on how fast it is drained. One can give up about 41% of the available energy when extracting the energy at a 30 milliwatt rate (30 millijoules/second) versus a 3 milliwatt rate (3 millijoules/second).

The-Week

THE WEEK June 12, 2015 pg 32

Tesla Motors is a company founded by Elon Musk that offers electric cars for sale. Musk has also founded Solar City, and Space X. These companies, especially the last one, are championed as commercial, but the capital involved is largely provided by the public.

Perhaps the most important and costly component of an electric car is the battery. Electric cars were very popular in the early 20th century. Oliver Parker Fritchle (1874-1951) of Denver Colorado offered electric cars and wind power generation in this period. According to Wikipedia:

Fritchle achieved national celebrity for his 1908 Lincoln-to-New York endurance run in one of the first electric automobile models produced by his firm.[5] He covered the 1,800 miles (2,900 km) in a stock Victoria Phaeton achieving as many as 108 miles (174 km) between charges[6] through extremes in weather, terrain, and road conditions; a remarkable feat with an electric vehicle of that day. The trip journal and photographs subsequently published to promote The 100 Mile Fritchle Electric provided unique insight to the state of road and electric power infrastructure within the United States during the early twentieth century.[7]

Fritchle_milostatFritchle even designed brakes that reclaimed the lost kinetic energy and diverted it into the battery. His car achieved about 100 miles between charges with lead-acid batteries. An attached hydrometer indicated the amount of charge left in the battery. The Tesla Roadster achieves about 244 miles per charge with lithium-ion batteries.

Sven related that Johnny Carson once interviewed Maude Tull, who was a few years over 100 at the time, and Maude recalled how much she liked her electric car. Maude did not believe in charging the battery completely. She left it charged for about thirty miles or so in case someone stole it, they could not get far before the police would catch them.

While Fritchle did not dabble in solar energy in the early twentieth century, Sven pointed out that Edwin Cawston did, using it to power his Ostrich Farm. Aubrey Eneas was the man behind the harnessing of Golden State sunshine and started the Solar Motor Company in downtown Los Angeles. According to the LA Times:

Eneas installed the six-story high apparatus on a sunny hillside in 1901. The device, which resembled a radar dish, was 33 feet in diameter at its widest point and lined with 1,788 mirrors. The mirrors funneled the sun’s rays onto a boiler containing 1,000 gallons of water. The resulting steam was used to power an engine that pumped between 1,400 and 1,500 gallons of water a minute from a deep well on the farm. The dish was attached to a track on a supporting tower so it could be kept trained on the sun.

The monstrous magnifier only heightened the farm’s exotic quality. “No extra charge to see the Solar Motor!,” declared printed handbills. “The only machine of its kind in the world in daily operation! 15-horsepower engine worked by the heat of the sun!”

Solar_Power_Ostrich

1902 (SMU Libraries)

This introduction has been a prelude to discussing the “newfangled” Tesla Powerwall battery:

Tesla-millimetersThis battery is to be used to “Provide energy storage for a sustainable home.” There are two versions of this home battery, one has an “energy capacity” of 10 Kilowatt-hours and the other is 7 Kilowatt-hours. At least we are closer to describing energy than when using Ampere*hours. I must give Tesla some positive prose for giving the metric size of the battery in millimeters (1300 mm x 860 mm x 180 mm). These two values of “energy” in terms of energy are:

10 kWh (36 Megajoules)
7   kWh (25 Megajoules)

New Scientist May 9, 2015 (click to enlarge)

New Scientist May 9, 2015 (click to enlarge) Meet the new battery, same as the old battery.

In a previous blog I argued that using joules exclusively on energy bills would make them very transparent to consumers. I use both electricity and natural gas in my home. We will just look at my electricity usage for comparison. In the month I used as an example, my usage was about 3.2 Gigajoules of energy for the month. Assuming a 31 day month I use about 103 Megajoules of electrical energy per day or 4.3 Megajoules per hour. This battery would provide my home with just over eight hours of power. This amount of energy is large enough to make it through many power outages, but it is not any type of panacea for the storage of solar energy. A more thorough examination of the Tesla Power Wall has been undertaken by Dan Steingart and may be found here.

The larger point, once again, is that it seems reasonable to use energy to describe energy (joules), and energy flow to describe energy flow (watt = joule/second). People do not describe public water towers in terms of Kiloliter-hours of water, they (if they are refined persons who use the metric system) would describe the water tower capacity in Kiloliters period (2000 Kiloliters for the largest spherical water tower in the US).

The joule, when used appropriately, describes the amount of energy in a sandwich, a battery, my monthly electrical usage, or even the energy of an asteroid strike. The June 2015 issue of Astronomy magazine has an article by Eric Betz entitled To Catch a Shooting Star. This article includes a very nice NASA map of asteroid/meteorite impacts and their associated energy in Gigajoules:

Asteroids-Joules

(The energy use of a typical household is probably about 1-10 GJ per month.)

We have an excellent unit of energy that can be used for universal comparison, the joule, it’s just too bad we want to describe our energy in metaphors that masquerade as numerical information, rather than just presenting numerical information and informing ourselves and the public.

The Metric System & Scientific “Communicators”

Archer-Fanged-Deer-SmallBy The Metric Maven

Bulldog Edition

The skeptic does not mean he who doubts, but he who investigates or researches, as opposed to he who asserts and thinks that he has found.

             – Miguel de Unamuno

For many years I had been directly involved in scientific skepticism, which is often found under the rubric of “skeptics” these days. The organization for which I volunteered was disbanded a number of years back. It was this vacuum of spare time which allowed me to return to my interest in the promotion of the metric system. I had not thought about the Skeptics much for a number of years until my friend Kat, and another long-time Skeptics friend Ollie suggested I listen to the Skeptics Guide To The Universe podcast.

I was surprised at how interesting I found the program, and I began to listen to it regularly. Then a few notes of measurement discord surfaced. I used their online form to request they stick with metric and also most definitely stop quoting inches and centimeters and go with millimeters exclusively for a small metric unit. I linked to a number of my essays on the subject of millimeters versus centimeters.

I have emailed other programs, podcasts and such, and generally encounter silence. I was rather surprised when it appeared that someone actually read my online form submission (as I don’t have a copy I can’t review what I actually said).

Their podcast Episode #486 2014-11-08 actually acknowledged my submission. The subject under consideration was the Fanged Deer (25:53), here is my own attempt at a transcription:

Steve: Evan, I’m looking at a very cool picture of a vampire deer. Or something like that—tell me about this.

Evan: Uh Vampire deer, yeah well—well Steve and folks I’m sure you’ve heard of let’s say the white tailed deer. Right? we’ve all heard of that pretty common. We’ve probably heard of the Red Deer maybe, or you’ve even heard of a Reindeer, and you even heard “do” a deer at some point in your life.

Steve: Buck (?)

Evan: But—but I defy the SU listener to have ever heard of a Kashmir Musk Deer at least prior to recent news headlines. Uh and because you have probably never heard of this species of deer before and-there whose official taxonomical designation is Moschus cupreus it’s a one of seven Moschidae species found in Asia. Um, this Kashmir Musk Deer is uh in fact quite an interesting animal in that the males of the species grow tusks and the tusks can grow as long as ten centimeters—or rather what is that a hundred millimeters—because someone told us recently that centimeter measurements is rubbish—who is it who that said that?.

Steve: Yeah, some metric fanatic. [laughing]

Evan: Yeah–that’s right [laughter]

Steve: Yeah, he made a reasonable argument but it was his point was that centimeters are confusing and the only reason people only use them because they’re sort of inches but [laughter] for conversion purposes just sticking with millimeters is less confusion.

Evan: Right—so a hundred millimeters let’s call it.

Steve: Allright.

Evan: And of course what with Halloween just recently cominal(?) they’re being called in the news as vampire deer.

I was chagrined to be called a metric fanatic, which appeared to have been in a rather haughty and dismissive manner. I emailed SGU and also pointed out that I had been involved with scientific skepticism for many years before I began my metric quest.

Australia-Rain

— click to enlarge

The SU group then took a trip to Australia, which I hoped might actually cause them to notice they were in a metric country which speaks English. They also visited New Zealand, and did not seem to find it novel to order steaks in grams and drinks in milliliters. Perhaps they didn’t eat or drink while they were there? It will probably not come as a surprise to my readers that the mention of millimeters on the SU podcast was fleeting, and an examination of clear metric usage by the panel of scientific communicators was apparently of little interest.

The podcast has continued to use centimeters, inches, microns, and whatever units are the path of least intellectual resistance for their segments. I have emailed them about numerical presentation, but now I’m just dismissed as “some metric fanatic”—like a follower of Eric Von Daniken, Charles Berlitz, Uri Geller, Jenny McCarthy. or Charles Piazzi Smyth. I found it strange that the same manner of dismissive attitude which paranormal enthusiasts have used to dismiss scientific skeptics was employed by SGU toward me. It’s strange to see these promoters of science taking the same line toward the metric system as John Bemelmans Marciano does in his recent celebration of failure.

The phrase critical thinking is generally employed by Skeptics to describe what they are promoting and what they do. Skeptics also assert they are promoting science. Critical thinking relies on informing oneself about a subject and evaluating available information. It appears that when it comes to the metric system, the panelists of the Skeptics Guide to The Universe (SGU) apparently have already decided that the matter of a measurement policy for their show is trivial. They’ve already learned all they need to know by osmosis and so it requires no examination, investigation or self-education.

Steven Novella (Steve in the dialog above) has produced a video for The Great Courses, which has also been promoted on the SGU program. Its title is Your Deceptive Mind: A Scientific Guide to Critical Thinking Skills. One of the subjects examined in the video (which I don’t have, nor have I seen) according to Steven Novella is innumeracy. A person who claims expertise in numeracy and laughs when questioned about the most intuitive use of the metric system for numerical presentation? Wow, I don’t know what to say. I cannot not even construct a sentence in response.

I would suggest Steve Novella consider looking at some of my essays for some numerical guidance. My essay One Hundred is Everywhere delves into fuel efficiency and how it might best be expressed in liters per 100 Kilometers rather than Kilometers per liter. That seems like a reasonable topic for discussion. I address the poor expression of numerical information in my review of the book The Story of Measurement. Other relevant essays on numerical presentation are: Joule in the Crown, Technical Presentation and Metric, A Kilotonne is How Much in Metric?, American Software vs Metric, Feral Units Endanger Our Health, and Don’t Get  Engaged with Gauge.

In my emails to SGU, I provided a number of links to what I believe to have been important basic metric articles I’ve written and linked to Naughtin’s Laws. I pointed out to SGU that if they did not believe me, they should look at what Pat Naughtin left behind—in his videos and writing. I included links to Pat’s works. Perhaps they might even look at the monograph Metrication in Australia?—to help them with any critical thinking they might like to do with respect to the most effective use of the metric system for technical presentation. Perhaps The Skeptics Guide To The Universe might even question—as I have-–how astronomers present distances.

The catch phrase “science communicator” has commonly been invoked in recent SGU broadcasts. This appears to be an expertise they claim to possess. It appears to me, that to communicate science, one should examine how numerical information is best presented, and what the clearest format one might use to provide intuitive numerical information might be. Have they investigated Pat Naughtin’s whole number rule? Have the SGU members thought about the use of metric prefixes to make astronomical distances more understandable to everyone? Could it be that using the light year is just an obfuscating gee-whiz! unit that does not provide context?—of course not, no critical thinking needed there—case closed. How about examining the history of the metric system for unnecessary 19th century? baggage—for example the demi-dekagram and demi-deciliter. Have they ever wondered why chemists don’t use centiliters, or deciliters, but do use milliliters?

I’ve discovered that numerical values are not used on SGU nearly as often as one might think, but when they are, they are not optimum in my view. Here are some of the numerical presentations I’ve found rather cringe-worthy:

SGU on 2015-02-02

During a discussion of the close approach of asteroid 2004 BL86 it was stated that it was within 745,000 miles or 1.2 million Kilometers. They then state that this is 3.1 times the distance from the Earth to the moon. There is a useful metric prefix Mega,  to describe this nearest asteroid distance; which would make it 1200 Megameters. The distance of the Earth from our moon is 384 Megameters. The relative magnitudes are rather clear when one uses integers and an appropriate metric prefix.

During a discussion of the size of wormholes it was stated that theoretical values range down to 10-33 centimeters. The range of metric prefixes goes down to yocto which is 10-24 meters. The values are clearly outside of the range of metric prefixes. Why on Earth would centimeters be used as a base unit?—particularly in scientific notation. Does it add anything other than a comforting bit of non-information? How about 10-35 meters? How small is this? Well the linear cross-section of lower energy neutrinos is thought to be somewhere around 20 yoctometers which is 20 x 10-24 meters. The smallest wormhole is about 100 000 000 000 or 100 billion times smaller than the realm of a neutrino, or 100 Megatimes smaller. Why the centimeters?—are they being passive aggressive?—or sloppy?

SGU on 2015-03-21

While describing the computer cluster that will be used with the Large Hadron Collider, petabytes, gigabytes and one participants favorite, yottabytes, were used. When metric prefixes are received wisdom, they are employed without critical regard.

SGU on 2015-04-07

It was noted that global warming/climate change had increased the amount of vegetation on Earth such that 4 billion tons of carbon had been sequestered, but 60 billion tons of carbon were released over the same period. [It isn’t clear from the audio if they mean tons or tonnes] These values are about 4 Petagrams and 60 Petagrams respectively. Oil production worldwide each year is on the order of 4 Petagrams, and the total amount of carbon in the Earth’s atmosphere is approximately 720 Petagrams. There was no attempt to use metric in this segment of the show, but as soon as computer storage was broached, Terabytes and such quickly appeared.

Then this strange exchange occurred on 2015-04-18. The “science communicators” discuss the innate fear of spiders that most humans possess. Then the SGU members introduce some “scientific levity.” I have been unable to separate out the voices:

“I believe that we’ve all seen an example of the purple recluse spider.”

“Ah yes, It has a bow tie shape on it’s neck region.”

“They live in dark tunnels, they do, and uh they’re bottom feeders essentially [laughter]…..and, and,  and they absolutely adore the metric system, from what I hear.

“They only move in millimeters. It’s weird.”

I have no idea if this statement is aimed at your friendly neighborhood Metric Maven and his purple masthead, but I find the shot at the metric system by “science communicators” sad, and if its aim was wider than that, then I suggest these “science communicators” read up on the definition of ad hominem attack.  It may be my sensitivity, but there were then a number of centimeters thrown in, seemingly with emphasis, for “good measure.” Well, correlation does not necessarily imply causality. I could be experiencing confirmation bias. It is a strange set of “science communicators” who take the metric system as a source of amusement. Apparently they cannot be bothered to investigate the metric system, or at a minimum watch Pat Naughtin’s Google video.

SGU on 2015-04-25

During a discussion of the Large Hadron Collider (LHC) this exchange occurred:

Brian Wecht: “I wrote this down let me check yeah—was up to 4 Tev—Teraelectron-volts ok, which is just some unit of energy that’s a lot it, it was a record setting beam, when they turned it on, and some of that energy in the beam right the protons collide and annihilate…..”

Steve Novella: “Let’s put this into a frame that people  understand—how quickly would that pop a jiffy pop popcorn?

Brian Wecht: Super fast dude!—crazy fast

Person 1: “Mega” [talking over one another] “in an attosecond.”

[talking over one another]

Later in the conversation:

Brian Wecht: “…..”They got up to 6.5 Tev”

And Later, after a discussion of the possibility of the LHC creating a black hole was discussed, this was said:

Person 2: “We could go now two years, three years of these 14 Terawatt beams smashing into each other and we could see nothing…”

An electron-volt (ev) is equivalent to 1.6×10−19 joules (160 zJ). A Teraelectron-volt is therefore 160 nanojoules. How much energy is in a joule? If one has a small apple, which is about 100 grams and it is dropped from the height of a doorknob (about 1 meter), the energy it has when it strikes the floor is approximately a joule.  A Teraelectron-volt is 6 125 000 times smaller than the amount of energy the apple possesses when it hits the floor after dropping from the height of a door handle. This is a tiny amount of energy, and a Tera-ble use of the prefix Tera.

The answer as to how long it would take to pop a jiffy pop popcorn is—-infinity. I suspect a Teraelectron-volt is more akin to the energy of a metaphorical butterfly sneeze. It could not pop a single kernel of popcorn—nor could 6.5 Tev—which is 1040 nanojoules. Wikipedia states that the kinetic energy of a flying mosquito is about 160 nanojoules. Not a single kernel of popcorn will be exploded when absorbing a Teraelectron-volt of energy, nor would  a flying mosquito probably possess the energy to produce a black-hole I suspect. A Tev may be a large amount of energy for a subatomic particle, and its interactions, but on the macroscopic level, it’s infinitesimal.

A garden variety micrometeorite has a mass of about 50 micrograms, and travels at a velocity of about 10 Kilometers per second. The kinetic energy of this example micrometeor is 15.63×1018  electron-volts or 15.63 Exaelectron-volts or 15.63 Eev. This kinetic energy value is two metric prefixes larger in magnitude (1 000 000) than the 6.5 Tev quoted in SGU for subatomic particles—this garden variety micrometorite has far more energy than the LHC imparts to subatomic particles. In everyday terms the energy in the example micrometeor  is 2.5 joules.

I’m unable to identify Person 2. I have no idea where the 14 Terawatt value originated, but watts are units of power. Power, for us “metric fanatics,” is a joule per second. In one second this would be 14 000 000 000 000 joules of energy or 14 Terajoules. For reference the atomic bomb which exploded over Hiroshima released about 63 Terajoules of energy. It is probable that this was just a quick mistake during the rapid fire exchanges, but it is a big one.  The other “Science Communicators” should have possibly taken note, but did not. They were too busy making science “fun.”

SGU on 2015-05-23

The SGU members describe a new beam splitter for light which is much smaller than previous designs, and assert that it’s a great breakthrough for photonic computing (later in their farrago of talk they seem to question this assertion). SGU’s discussion of photonic computing is so muddled and painful to listen to, that I have not attempted to make a transcript and my comments would constitute another essay entirely. Jay states: “…photonic computing: it uses photons in the visible or infrared light spectrum….” Perhaps at this point they might have pointed out that light waves in the visible spectrum have wavelengths in the nanometer range, say about 500 nanometers or so (or 500 millimicrons to stay SGU-inconsistent). The SGU interlocutors quote current beam splitters as being about 100 by 100 microns, and the new beam splitter is about 2.4 by 2.4 microns. They use the non-descriptive term micron for micrometers. The use of microns only serves to obfuscate and does not provide magnitude context or information.

Jay then states:

Jay: And to give you an idea about how small this is, its about one-fiftieth of a human hair—so it’s not even visible.

Bob: An angel can’t even dance on the tip of it.

I very much like comparisons of this type, but a context with light would be useful. A human hair has considerable variation (17-181 μm), but one can say it’s about 100 micrometers in diameter as an overall estimate.  The current beam splitter design has about the same cross-section as a hair. The new beam-splitter is about 3 x 3 micrometers. But what about light?  The size of the baseline beam splitter is originally 100 000 x 100 000 nanometers, it is now 2400 x 2400 nanometers. A representative wavelength of visible light is on the  order of 500 nanometers. This is why one can’t go much smaller and still illuminate the beam splitter, and still have it operate as a beam splitter. The members of the SGU apparently can’t bring themselves to do something other than just parrot back microns, as they probably read in the media, and continue to propagate poor measurement exposition without a second thought. Pun intended.

• • •

This scientific blind-spot, that these “scientific communicators” have for using the metric system carelessly, is not unique to SGU, it exists in all of engineering and science. If you sense my frustration, it is because a tool is being misused, and being subjected to sanctimonious dismissal by “scientific professionals,” “scientific communicators,” and others at SGU. If The Skeptic’s Guide to The Universe were Fate magazine, I would not bother to point out its faults, but I’ve been on the side of scientific skepticism all of my life. Since I began to listen to the SGU podcast, I don’t recall any of the regulars ever expressing remorse or concern that the US does not use the metric system. They managed to visit Australia and not note the use of the metric system in almost every aspect of everyday life. I find it vexing and dispiriting when people that represent a group I once spent so much of my  volunteer time with promoting science, greets the metric system with the same indifference as those who don’t claim to have any expertise in science whatsoever, and then call themselves skeptics. E tu Skepti?